Abstract of the project
Organic air contaminants (both indoor and outdoor) have been studied for a long time due to their toxic and climate-altering properties; among the volatile compounds (VOCs) some develop toxicity in the short term, but many are toxic in the medium to long term (carcinogenicity and mutagenicity). As an example of this we can mention mono-aromatic hydrocarbons (benzene, styrene, etc.), and polycyclic aromatic hydrocarbons (PAHs), which are particularly harmful also because they are often associated with ultra-fine powders. For workplaces, there is extensive legislation at European and national level, which indicates in addition to the concentration limits on various time scales, also the procedures and devices designed to mitigate exposure to these compounds and the methods to be followed to make environmental measurements. . It has also been shown that numerous VOCs are produced by the metabolism of fungi and bacteria (MVOCs: microbial volatile organic compounds).
necessary condition to limit risks in real time and support decision-making processes by security managers. In addition to the detection, the instruments currently in use also hardly allow the sampling of the various pollutants, in particular those associated with fine dust, for subsequent more accurate analyzes to be carried out in the laboratory.
This project therefore proposes the development of compact, modular and low-cost sensory systems, for the real-time analysis of chemical and / or biological pollutants that can be optimized for the various work environments. These systems will consist of subsystems that can be assembled according to needs: volatile compounds sensors, solid sample analyzers, gas and dust samplers, preconcentration meters for volatile compounds, interface electronics and communication systems, data processing and presentation software. The communication electronics will be based on wireless mode. Low consumption electronic systems will be privileged in order to guarantee complete portability. For this purpose, mobile devices such as tablets and smart-phones will be considered for data presentation and information management. In the initial phase of the project, the possible application scenarios, the volatile substances of interest and the main interferents to be considered will be selected. An example of application will concern the monitoring of styrene, a characteristic pollutant in fiberglass processing plants and in the automotive industry. The possibility of monitoring some microorganisms through the analysis of volatile metabolites will also be investigated. The possibility of installing compact sensory systems on autonomous vehicles, eg, mini-robots or drones, will also be analyzed for the inspection of high-risk areas, such as post-fire scenarios or industrial environments following contaminant leaks.
1) compactness, portability and low cost; fundamental characteristics to favor the widespread diffusion of these safety devices in the greatest number of workplaces; ensure the collection of a large number of data in real time for more accurate subsequent analyzes and for the generation of risk models; possibility of placing these systems on self-driving vehicles, eg, robots or drones, for monitoring high-risk environments, following emergencies, where human accessibility must be limited (post fire, leaks of highly toxic pollutants, etc. .);
2) transfer of information in real time through wireless communication technologies. Graphic interface for displaying maps of the distribution of pollutants measured by sensors on mobile supports such as tablets and smartphones with automatic alert procedures, if necessary;
3) possibility of sampling pollutants on dedicated supports for in-depth ex-situ analysis;
4) possibility of pre-concentration based on purge-and-trap technology to improve the detection threshold of compounds of particular interest.
• Department of Sciences, University of Rome 3;
• Institute on Atmospheric Pollution, National Research Council
• DIMEILA - INAIL Chemical Agents Risk Laboratory
Angel Cecinato
Emiliano Zampetti
Alessandro Capocecera
Joshua Avossa
Catia Balducci